Sodium hydride

Agent Name
Sodium hydride
CAS Number
7646-69-7
Formula
H-Na
Major Category
Metals
Synonyms
NaH; Sodium monohydride; UN1427; [ChemIDplus]
Category
Metal Hydrides
Description
Gray powder in oil with a kerosene odor; [CHRIS]
Sources/Uses
Used as a condensing and reducing agent, e.g., to descale metals by reducing metal oxides; [HSDB]
Comments
Can cause third-degree burns after short contact; [CHRIS] Highly corrosive to skin, eyes, and respiratory tract with risk of acute pneumonitis and pulmonary edema after high inhalation exposure; reacts with water to form sodium hydroxide and hydrogen; [HSDB] Hydrides are one of the four binary salts that have specific hazards (nitrides, carbides, hydrides, and phosphides); Hydrides give off hydrogen, and a corrosive base is formed from contact with water. The corrosive base is the hydroxide of the metal that is attached to the hydrogen in the hydride compounds; [Burke, p. 21]
Biomedical References

Exposure Assessment

NFPA
may ignite at ambient temp

Adverse Effects

Toxic Pneumonitis
Yes
Dermatotoxin
Skin burns

Diseases, Processes, and Activities Linked to This Agent

Other Information
No other related information on this agent was found.