Agent Name
Barium permanganate
Synonyms
Barium manganate(VII); Permanganate barico [Spanish]; Permanganate de baryum [French]; Permanganic acid (HMnO4), barium salt; Permanganic acid, barium salt; UN1448; [ChemIDplus]
Category
Metals, Inorganic Compounds
Description
Dark purple to black solid; [CHRIS] Soluble in water; [HSDB]
Sources/Uses
Used as a dry cell depolarizer, disinfectant, and intermediate for the production of other permanganates; [HSDB]
Comments
A skin an eye irritant; [CHRIS] Toxic by ingestion causing abdominal pain, vomiting, and shortness of breath; [CAMEO] Permanganates can induce methemoglobinemia after ingestion; [Olson, p. 133] See "Potassium permanganate"; See "Barium, soluble compounds." See "Manganese" and linked occupational diseases.
TLV (ACGIH)
0.5 mg/m3, as Ba, 0.02 mg/m3, as Mn (respirable fraction), 0.1 mg/m3, as Mn (inhalable fraction)
PEL (OSHA)
0.5 mg/m3, as Ba, Ceiling(OSHA) = 5 mg/m3, as Mn
MAK
0.5 mg/m3, as Ba, inhalable fraction(soluble compds), 0.2 mg/m3, as Mn (inhalable fraction), 0.02 mg/m3, as Mn (respirable fraction)
IDLH (NIOSH)
50 mg/m3, as Ba
Methemoglobinemia
MetHgb is secondary toxic effect
Hepatotoxin
Hepatoxic (a) from occupational exposure (secondary effect) or (b) in animal studies or in humans after ingestion
ACGIH Carcinogen
Not Classifiable
Diseases
Occupational diseases associated with exposure to this agent:
Processes
Industrial Processes with risk of exposure: