Ferbam

Agent Name
Ferbam
CAS Number
14484-64-1
Formula
C9-H18-Fe-N3-S6
Major Category
Pesticides
Ferbam formula graphical representation
Synonyms
(OC-6-11)-tris(dimethylcarbamodithioato-S,S')iron; Aafertis; Aaferzimag; Bercema fertam 50; Carbamic acid, dimethyldithio-, iron salt; Carbamic acid, dimethyldithio-, iron(3+) salt; Carbamodithioic acid, dimethyl-, iron complex; Cormate; Dimethylcarbamodithioic acid, iron complex; Dimethylcarbamodithioic acid, iron(3+) salt; Dimethyldithiocarbamic acid, ferric salt; Dimethyldithiocarbamic acid, iron salt; Dimethyldithiocarbamic acid, iron(3+) salt; Eisen(III)-tris(N,N-dimethyldithiocarbamat) [German]; Eisendimethyldithiocarbamat [German]; Ferbam; Ferbam 50; Ferbam, iron salt; Ferbame [ISO-French]; Ferberk; Fermacide; Fermate; Fermate ferbam fungicide; Fermocide; Ferradow; Ferric dimethyldithiocarbamate; Fuklasin; Fuklasin Ultra; Fuklazin; Hexaferb; Hokmate; Iron dimethyldithiocarbamate; Iron tris(dimethyldithiocarbamate); Iron(III) dimethyldithiocarbamate; Iron, tris(dimethyldithiocarbamato)-; Karbam Black; Knockmate; Liromate; Niacide; Stauffer ferbam; Sup'R-flo ferbam flowable; Trifungol; Trimanzone; Tris(N,N-dimethyldithiocarbamato) iron(111); Tris(N,N-dimethyldithiocarbamato)iron(III); Tris(dimethylcarbamodithioato-S,S')iron; Tris(dimethyldithiocarbamato)iron; Vancide FE95; [ChemIDplus]
Category
Dithiocarbamates (Pesticide)
Description
Dark brown to black, odorless solid. [fungicide]; [NIOSH]
Sources/Uses
Fungicide used on fruit, nuts, vegetables, ornamental crops, in household applications; [HSDB]
Comments
The EBCDCs (ethylenebisdithiocarbamates) can cause irritant and allergic contact dermatitis. EBDCs include ferbam, vapam, maneb, mancozeb, zineb, thiram, and ziram. They are also used as rubber accelerators. Ethylene thiourea (ETU), which may contaminate EBCDCs, is carcinogenic and teratogenic in animal experiments. [LaDou, p. 610] ETU is the major metabolite of EBDCs. [Krieger, p. 1690] See the agent, "Ethylene thiourea."
Reference Link #1
Biomedical References

Exposure Assessment

Skin Designation (ACGIH)
Insufficient data
TLV (ACGIH)
5 mg/m3 (Inhalable fraction)
PEL (OSHA)
15 mg/m3, total dust
IDLH (NIOSH)
800 mg/m3
Excerpts from Documentation for IDLHs
Human data: Large oral doses cause gastrointestinal disturbances [Proctor et al. 1988]. The dust is irritating to the eyes and respiratory tract; severe exposures are expected to cause depression of the central nervous system [Proctor et al. 1988].
Vapor Pressure
2.73E-10 mm Hg
Explanatory Notes
VP is negligible; [HSDB]
Reference Link #2

Adverse Effects

Skin Sensitizer
Yes
Reproductive Toxin
Yes
IARC Carcinogen
Not classifiable
ACGIH Carcinogen
Not Classifiable

Diseases, Processes, and Activities Linked to This Agent

Diseases

Occupational diseases associated with exposure to this agent:

Processes

Industrial Processes with risk of exposure: