Nickel(II) ferrocyanide

Agent Name
Nickel(II) ferrocyanide
CAS Number
14874-78-3
Formula
C6-Fe-N6-Ni2
Major Category
Metals
Nickel(II) ferrocyanide formula graphical representation
Synonyms
Nickel ferrocyanide; Dinickel hexacyanoferrate; Ferrate(4-), hexakis(cyano-C)-, nickel(2+) (1:2); [ChemIDplus]
Category
Nickel Compounds, Inorganic
Sources/Uses
The ferrocyanides are used in the production of blue pigments with the potassium salt used in Europe and the sodium salt used in the United States; Sodium and calcium salts used for uncaking of NaCl; Potassium salts used in refining of wine and photographic industry; [Ullmann]
Comments
Ferrocyanide complexes are stable and practically nontoxic because of the strong bonding between iron and cyanide. Cyanide ions may be formed slowly when the chemical is irradiated with UV light. [Ullmann] See "Nickel" and linked occupational diseases.
Biomedical References

Exposure Assessment

TLV (ACGIH)
0.1 mg/m3, inhalable fraction, as Ni
PEL (OSHA)
1 mg/m3, as Ni
IDLH (NIOSH)
10 mg/m3, as Ni

Adverse Effects

Skin Sensitizer
Yes
Asthma
Yes
Other Poison
Chemical Asphyxiant

Diseases, Processes, and Activities Linked to This Agent

Diseases

Occupational diseases associated with exposure to this agent: