Hydrogen peroxide

Agent Name
Hydrogen peroxide
CAS Number
7722-84-1
Formula
H2-O2
Major Category
Toxic Gases & Vapors
Synonyms
Albone; Albone 35; Albone 35CG; Albone 50; Albone 50CG; Albone 70; Albone 70CG; Albone DS; Dihydrogen dioxide; Elawox; Hioxyl; Hydrogen dioxide; Hydrogen dioxide solution; Hydrogen peroxide; Hydrogen peroxide (H2O2); Hydrogen peroxide solution (DOT); Hydrogen peroxide, 90%; Hydrogen peroxide, solution; Hydrogen peroxide, solution, 3%; Hydrogen peroxide, solution, 30%; Hydrogen peroxide, solution, 35%; Hydroperoxide; Inhibine; Interox; Kastone; Lensept; Oxydol; Perhydrol; Perone; Perone 30; Perone 35; Perone 50; Perossido di idrogeno [Italian]; Peroxaan; Peroxan; Peroxide; Peroxyde d'hydrogene [French]; Superoxol; T-Stuff; UN 2014 (20%-52%); UN 2015 (>52%); UN 2984 (8%-20%); [ChemIDplus]
Category
Oxidizers
Description
Colorless liquid with a slightly sharp odor. [Note: The pure compound is a crystalline solid below 12 degrees F. Often used in an aqueous solution.]; [NIOSH]
Sources/Uses
Used for the bleaching, disinfecting, and producing other chemicals; H2O2 is used in the textile, wood pulp, food, hairdressing, fur, and water treatment industries; [ACGIH] Used in photography (hypo eliminator); [www.ci.tucson.az.us/arthazards/medium.html] Used in the deliming and dyeing stages of leather production; [PMID 21938525]
Comments
Liquid causes second degree burns after a few minutes of contact; [CHRIS] Hydrogen peroxide 30-70% is corrosive to the skin. [Quick CPC] "When used for household disinfectant purposes (3% to 5%), it is mildly irritating to the skin and mucous membranes. At a concentration of 10%, which is found in some hair-bleaching solutions, it is strongly irritating and may be corrosive." [ATSDR Medical Management] Corrosive to the skin and eyes and irritating to the respiratory tract; [ICSC] Hydrogen peroxide solutions 35% and greater could cause pulmonary edema after inhalation; [CHEMINFO]
Biomedical References

Exposure Assessment

Skin Designation (ACGIH)
Insufficient data
TLV (ACGIH)
1 ppm
PEL (OSHA)
1 ppm
MAK
0.5 ppm
IDLH (NIOSH)
75 ppm
Excerpts from Documentation for IDLHs
Other animal data: It has been reported that mice tolerated a single 4­hour exposure to 75 ppm [Svirbely]. \ Human data: It has been stated that although the short­term exposure tolerance is unknown, it is probably about 75 ppm [AIHA 1957]. Death has resulted in a man who drank 100 ml [Raukhverger and Solodko 1974].
Vapor Pressure
1.97 mm Hg
Lethal Concentration
LC50 (rat) = 2,000 mg/m3/4 hr
Explanatory Notes
The Guide from the Emergency Response Guidebook is for "hydrogen peroxide, aqueous solution, stabilized, with more than 60% Hydrogen peroxide." VP from HSDB.
NFPA
will not burn
ERPG-1
10 ppm
ERPG-2
50 ppm
ERPG-3
100 ppm

Adverse Effects

Toxic Pneumonitis
Yes
Dermatotoxin
Skin burns
IARC Carcinogen
Not classifiable
ACGIH Carcinogen
Confirmed Animal

Diseases, Processes, and Activities Linked to This Agent

Activities

Activities with risk of exposure: