Diborane

Agent Name
Diborane
CAS Number
19287-45-7
Formula
B2-H6
Major Category
Toxic Gases & Vapors
Diborane formula graphical representation
Synonyms
Boroethane; Boron hydride; Diboron hexahydride; Diborane; [ChemIDplus] UN1911
Category
Hydrides
Description
Colorless gas with a repulsive, sweet odor; Note: Usually shipped in pressurized cylinders diluted with hydrogen, argon, nitrogen, or helium; [NIOSH] Vapor density = 0.96 (lighter than air); [HSDB]
Sources/Uses
Used as a rocket fuel, semiconductor doping agent, rubber vulcanizer, reducing agent, and polymerization catalyst; [ACGIH]
Comments
Listed as one of "major irritant airborne toxicants"; [LaDou, p. 563] Animals exposed to high concentrations develop respiratory irritation and pulmonary edema; [ACGIH] Corrosive to the skin and eyes; [ICSC]
Biomedical References

Exposure Assessment

Skin Designation (ACGIH)
Insufficient data
TIH
Yes
TLV (ACGIH)
0.1 ppm
PEL (OSHA)
0.1 ppm
IDLH (NIOSH)
15 ppm
Excerpts from Documentation for IDLHs
Human data: None relevant for use in determining the revised IDLH.
Odor Threshold Low
1.8 ppm
Odor Threshold High
3.5 ppm
Lethal Concentration
LC50 (rat) = 40 ppm/4H
Explanatory Notes
Odor threshold from AIHA; Flash point = -90 deg C;
Reference Link #2
NFPA
burn readily
ERPG-1
Not appropriate
ERPG-2
1 ppm
ERPG-3
3 ppm

Adverse Effects

Toxic Pneumonitis
Yes
Dermatotoxin
Skin burns

Diseases, Processes, and Activities Linked to This Agent

Diseases

Occupational diseases associated with exposure to this agent:

Processes

Industrial Processes with risk of exposure: