Working with Glues and Adhesives

Description

In the past, benzene was commonly used as a glue solvent in the shoe industry. N-hexane is another toxic solvent that has been used as a glue solvent. Urea-formaldehyde and phenol-formaldehyde glues are used in plywood and particleboard manufacturing. Epoxy resins, isocyanates, acrylates, and curing agents are also used to make synthetic glues and adhesives.

Category

Other

Agents

Hazardous agents associated with this process:

• Abietic acid, dihydro-, triester with glycerol
• Acacia
• Acetaldehyde
• Acetylethanolamine
• Acrylamide
• ACRYLIC RESINS (MONOMERS)
• Acrylonitrile
• Agar
• Alkenes, C12-24, chloro
• (C14-C18) Alkyl alcohol sulfuric acid sodium salt
• Ammonium perchlorate
• sec-Amyl acetate
• Arsenic pentoxide
• Asphalt, oxidized
• Azelaic acid
• Canada balsam
• Barium metaborate
• Benzene
• 1,2-Benzenedicarboxylic acid, di-C6-10-alkyl esters
• Benzophenone
• 2-(2H-Benzotriazol-2-yl)-4,6-di-tert-pentylphenol
• 1,3-Bis(1-isocyanato-1-methylethyl)benzene
• Bis(2-ethylhexyl) hydrogen phosphite
• Bis(2-methoxyethyl) phthalate
• Bis(trichloromethyl) sulfone
• Bisphenol A diglycidyl ether
• Bisphenol A-Bisphenol A diglycidyl ether polymer
• Bisphenol A-epichlorohydrin acrylate
• Bisphenol A-glycidyl methacrylate
• 2-Bromo-4-hydroxyacetophenone
• 1-Bromopropane
• Bronopol
• 1,3-Butadiene, polymer with 2-propenenitrile
• Butanal, reaction products with aniline
• 2-Butanone
• n-Butyl methacrylate
• n-Butyl propionate
• Butylated hydroxytoluene
• p-tert-Butylphenol formaldehyde resin
• Butyraldoxime
• C.I. Pigment Yellow 14
• C.I. Pigment Yellow 83
• Calcium chloride
• Calcium chloride hexahydrate
• Calcium sulfate dihydrate
• Carboxymethylcellulose Sodium
• Castor oil
• Castor oil, hydrogenated
• Chloral hydrate
• Chlorinated paraffins
• 1-Chloro-1-nitropropane
• Chlorobenzene
• m-Chlorobenzoic acid
• o-Chlorobenzoic acid
• p-Chlorobenzoic acid
• 4-Chlorophenol
• Chlorothalonil
• Collodion
• Copper(II) arsenite
• m-Cresol
• o-Cresol
• p-Cresol
• Crude oil
• 2-Cyanoethyl acrylate
• Cyclohexane
• Cyclohexanone
• Cyclopentane
• Decabromodiphenyl ether
• Dextrin
• Di-2-ethylhexyl maleate
• 2,2'-Dibenzothiazyl disulfide
• Dibutyltin oxide
• Dichlobenil
• 1,2-Dichloroethylene, all isomers
• Dicyclopentadiene dioxide
• 3-(Diethoxymethylsilyl)propylamine
• Diethyl hydrogen phosphite
• 2-(N,N-Diethylamino)ethyl methacrylate
• Diethylene glycol
• Diethylene glycol diacrylate
• Diethylene glycol diethyl ether
• Diethylene glycol dimethyl ether
• Diethylene glycol monobutyl ether acetate
• N,N-Diethyltrimethylenediamine
• 4-(Diglycidylamino)phenyl glycidyl ether
• Diiodomethyl p-tolyl sulfone
• Diisobutyl phthalate
• Diisocyanatomethylbenzene
• Diisopropanolamine
• 2-(Diisopropylamino)ethyl methacrylate
• Dimethoxane
• 2,2-Dimethoxy-2-phenylacetophenone
• 3,3'-Dimethoxybenzidine-4,4'-diisocyanate
• Dimethyl hydrogen phosphite
• N,N-Dimethylaminoethyl methacrylate
• Dimethylformamide
• 4,4-Dimethyloxazolidine
• 2,2'-Dimorpholinodiethyl ether
• Di-n-octyl phthalate
• Dipentamethylenethiuram disulfide
• Diphenyl cresyl phosphate (mixed isomers)
• Dipropylene glycol dibenzoate
• Distearyl pentaerythritol diphosphite
• Distillates (petroleum), hydrotreated heavy naphthenic
• DMDM hydantoin
• Dodecyl and tetradecyl glycidyl ethers
• Dodecylguanidine hydrochloride
• Epichlorohydrin
• EPOXY RESINS
• 1,2-Ethanediamine, polymer with 2-methyloxirane
• 1-Ethoxy-2-propanol
• 2-Ethoxyethanol
• 2-(2-Ethoxyethoxy)ethyl acetate
• 2-Ethoxyethyl acrylate
• Ethoxylated isooctylphenol
• Ethyl cellulose
• Ethyl cyanoacrylate
• (L)-Ethyl lactate
• Ethylbutyl thiourea
• Ethylene dichloride
• Ethylene glycol
• Ethylparaben
• Fatty acids, C18-unsaturated, dimers, polymers with 3,3'-(oxybis(2,1-ethanediyloxy))bis(1-propanamine)
• Fatty acids, C18-unsataturated, dimers, polymers with tall-oil fatty acids and triethylenetetramine
• Fatty acids, C18-unsaturated, dimers, reaction products with polyethylenepolyamines
• Fatty acids, tall-oil, reaction products with tetraethylenepentamine
• Formaldehyde
• Formaldehyde, polymer with 2-(chloromethyl)oxirane and 2-methylphenol
• Formaldehyde, polymer with 2-(chloromethyl)oxirane and phenol
• Formamide
• Furfural
• Furfuryl alcohol
• D-Glucopyranose, oligomeric, C10-16-alkyl glycosides
• Glycerol ester of rosin
• gamma-Glycidoxypropyltrimethoxysilane
• Glycidyl acrylate
• Glycidyl methacrylate
• Glycolic acid
• Glyoxal
• Grotan BK
• Heptabromodiphenyl ethers
• 1,2,5,6,9,10-Hexabromocyclododecane
• Hexabromodiphenyl ethers
• Hexamethylene tetramine
• n-Hexane
• 1,6-Hexanediol
• 1,6-Hexanediol diacrylate
• Hydrocarbon waxes, (petroleum), hydrotreated microcrystallized
• Hydrocarbons, terpene processing by-products
• 2-Hydroxyethyl methacrylate
• (Hydroxymethyl)urea
• 2-Hydroxymethyl-2-nitro-1,3-propanediol
• Hydroxypropyl methylcellulose
• Isobornyl thiocyanoacetate
• Isobutyl acetate
• Isobutyl acrylate
• Isobutyl vinyl ether
• Isobutyltrimethoxysilane
• Isodecyl acrylate
• Isophorone diamine
• Isophthalic acid
• N-Isopropylacrylamide
• Kaolinite
• Linseed oil
• Linseed oil, polymerized
• Magnesium chloride hexahydrate
• Melamine
• Menthol
• l-Menthol
• Mercapto mix
• Mercaptobenzothiazole
• Methacrylamide
• Methacryloyloxyethyl isocyanate
• Methyl 12-hydroxystearate
• Methyl 2-cyanoacrylate
• Methyl acrylate
• Methyl ethyl ketone peroxide
• Methyl isobutyl ketone
• Methyl methacrylate
• Methyl rosinate
• Methyl trimethylacetate
• N-Methyl-2-pyrrolidone
• Methylal
• Methylcellulose
• Methylchloro-isothiazolinone
• Methylene bisphenyl isocyanate
• 1,1'-Methylenebis(4-isocyanatobenzene) homopolymer
• Methylenediphenyl diisocyanate
• 2-Methylimidazole
• Methylisothiazolinone
• 4-Methylmorpholine 4-oxide
• N-Methylolacrylamide
• N-Methylolchloracetamide
• N-Methylolethanolamine
• Methyltetrahydrophthalic anhydride
• Methyltriacetoxysilane
• Methyltris(methylethylketoxime)silane
• 2-(4-Morpholinyldithio)benzothiazole
• Rubber solvent (naphtha)
• Naphtha (petroleum), hydrodesulfurized heavy
• Naphtha (petroleum), hydrotreated light
• Naphtha (petroleum), solvent-refined light
• Nitromethane
• 2-Nitropropane
• Nuosept 145
• Octamethylcyclotetrasiloxane
• Octylisothiazolinone
• ORGANIC SOLVENTS
• 2-Oxepanone, polymer with 2,2-bis(hydroxymethyl)-1,3-propanediol
• Oxirane, 2,2',2'',2'''-(1,2-ethanediylidenetetrakis(4,1-phenyleneoxymethylene))tetrakis-
• p,p'-Oxybis(benzenesulfonyl hydrazide)
• Paraffin waxes (petroleum), clay-treated
• Pentachlorophenol, sodium salt
• Pentaerythritol rosinate
• Pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate)
• Pentaerythritol triacrylate
• N,N,N',N',N"-Pentamethyldiethylenetriamine
• n-Pentane
• Pentasodium pentetate
• Pevikon
• Phenol
• Phenol, polymer with formaldehyde, glycidyl ether
• Phenoxarsine oxide
• Phenyl salicylate
• o-Phenylphenol
• Phenyltrimethoxysilane
• Phosphotungstic acid
• Picryl chloride
• Poly(oxy(methyl-1,2-ethanediyl)), alpha-hydro-omega-hydroxy-, ether with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol (3:1)
• Polyacrylic acid
• Polybutene
• Polyoxypropylene (10) glyceryl ether
• Polyvinyl acetate
• Polyvinyl alcohol
• Potassium N-hydroxymethyl-N-methyldithiocarbamate
• Potassium silicate
• Propene, 2-methyl-, homopolymer
• Propylene glycol monoethyl ether
• Propylene glycol mono-t-butyl ether
• Propylene phenoxetol
• Pyromellitic dianhydride
• Quaternium-15
• cis-Quaternium-15
• Residues (petroleum), vacuum
• Resin acids and Rosin acids, hydrogenated, esters with glycerol
• Resin acids and Rosin acids, sodium salts
• Resorcinol
• Rosin, maleated, polymer with pentaerythritol
• Safrole
• Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, reaction products with ammonia, octamethylcyclotetrasiloxane and silica
• Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica
• Silane, dichlorodimethyl-, reaction products with silica
• Sodium 2,4,5-trichlorophenolate
• Sodium hexafluorosilicate
• Sodium metaborate
• Sodium metasilicate
• Sodium metasilicate nonahydrate
• Sodium metasilicate pentahydrate
• Sodium omadine
• Sodium o-phenylphenol
• Sodium pentaborate
• Sodium silicate
• Solvent naphtha (petroleum), medium aliphatic
• Sorbitan sesquioleate
• Stearyl methacrylate
• Stoddard solvent
• Styrene-butadiene copolymers
• Sucrose octaacetate
• Tall oil
• Tall-oil pitch
• Tall-oil rosin
• Tetrachloroethylene
• Tetraethylene glycol
• Tetraethylene glycol diacrylate
• Tetrahydrofuran
• Tetraisopropyl titanate
• 2,4,7,9-Tetramethyl-5-decyne-4,7-diol
• Tetramethylthiourea
• Tetramethylthiuram monosulfide
• Thiabendazole
• Thiohexam
• Thiourea
• Titanium tetrabutylate polymer
• Toluene
• Toluene-2,6-diisocyanate
• Toluene diisocyanate
• Toluene-2,4-diisocyanate
• Toluenesulfonamide
• p-Toluenesulfonic acid
• p-Toluenesulfonyl isocyanate
• Tributyltin benzoate
• Tributyltin maleate
• Trichloroethane, all isomers
• 1,1,1-Trichloroethane
• 1,1,2-Trichloroethane
• Trichloroethylene
• 2,4,5-Trichlorophenol
• Triethanolamine
• Triethoxyoctylsilane
• 3-(Triethoxysilyl)propylamine
• Triethylenemelamine
• N-(3-(Trimethoxysilyl)propyl)ethylenediamine
• Trimethoxysilylpropyl methacrylate
• Trimethylolpropane ethoxylate
• Trimethylolpropane trimethacrylate
• Trimethylolpropane triacrylate
• 4,7,10-Trioxatridecane-1,13-diamine
• Tris(1-chloro-2-propyl)phosphate
• 1,1,1-Tris(4-hydroxyphenyl)ethane
• 2,4,6-Tris(dimethylaminomethyl)phenol
• Tristearin
• Urethane dimethacrylate
• gamma-Valerolactone
• Vinyl acetate/acrylate copolymer
• Vinyltriethoxysilane
• Xanthan gum
• Xylene isomers
• Zinc acetate
• Zinc caprylate
• Zinc propionate
• Zinc sulfate monohydrate
• Ziram